Skip to main content

Dope it with germanium: selective access to functionalized Si5Ge heterocycles

Koestler, Benedikt, Bae, Hyunwoo, Gilmer, Jannik, Virovets, Alexander, Lerner, Hans‐Wolfram, Albert, Philipp, Fantuzzi, Felipe, Wagner, Matthias (2023) Dope it with germanium: selective access to functionalized Si5Ge heterocycles. Chemical Communications, 59 (6). pp. 716-719. ISSN 1359-7345. (doi:10.1039/D2CC06060D) (Access to this publication is currently restricted. You may be able to access a copy if URLs are provided) (KAR id:99150)

PDF Author's Accepted Manuscript
Language: English

Restricted to Repository staff only until 13 December 2023.
Contact us about this Publication
[thumbnail of Authors Accepted Manuscript.pdf]
Official URL:
https://doi.org/10.1039/D2CC06060D

Abstract

The Cl– diadduct [nBu4N]2[A·2Cl] of the mixed cyclohexatetrelane (SiCl2)5(GeMe2), A, is accessible from Me2GeCl2, 6 eq. Si2Cl6, and 2 eq. [nBu4N]Cl in one step (96%). Free, tenfold functionalized A can be released from the primary product by decomplexation with AlCl3 (78%). Insight into the assembly mechanism of [nBu4N]2[A·2Cl] and the reactivity of A is provided.

Item Type: Article
DOI/Identification number: 10.1039/D2CC06060D
Uncontrolled keywords: Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Felipe Fantuzzi
Date Deposited: 14 Dec 2022 10:05 UTC
Last Modified: 27 Jan 2023 14:18 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/99150 (The current URI for this page, for reference purposes)
Koestler, Benedikt: https://orcid.org/0000-0001-8208-5471
Virovets, Alexander: https://orcid.org/0000-0002-8843-8503
Lerner, Hans‐Wolfram: https://orcid.org/0000-0003-1803-7947
Fantuzzi, Felipe: https://orcid.org/0000-0002-8200-8262
Wagner, Matthias: https://orcid.org/0000-0001-5806-8276
  • Depositors only (login required):

Downloads

Downloads per month over past year