Koestler, Benedikt, Bae, Hyunwoo, Gilmer, Jannik, Virovets, Alexander, Lerner, Hans‐Wolfram, Albert, Philipp, Fantuzzi, Felipe, Wagner, Matthias (2023) Dope it with germanium: selective access to functionalized Si5Ge heterocycles. Chemical Communications, 59 (6). pp. 716-719. ISSN 1359-7345. (doi:10.1039/D2CC06060D) (KAR id:99150)
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| Official URL: https://doi.org/10.1039/D2CC06060D |
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Abstract
The Cl– diadduct [nBu4N]2[A·2Cl] of the mixed cyclohexatetrelane (SiCl2)5(GeMe2), A, is accessible from Me2GeCl2, 6 eq. Si2Cl6, and 2 eq. [nBu4N]Cl in one step (96%). Free, tenfold functionalized A can be released from the primary product by decomplexation with AlCl3 (78%). Insight into the assembly mechanism of [nBu4N]2[A·2Cl] and the reactivity of A is provided.
| Item Type: | Article |
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| DOI/Identification number: | 10.1039/D2CC06060D |
| Uncontrolled keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 14 Dec 2022 10:05 UTC |
| Last Modified: | 13 Dec 2023 00:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/99150 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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