Koestler, Benedikt, Bae, Hyunwoo, Gilmer, Jannik, Virovets, Alexander, Lerner, Hans‐Wolfram, Albert, Philipp, Fantuzzi, Felipe, Wagner, Matthias (2023) Dope it with germanium: selective access to functionalized Si5Ge heterocycles. Chemical Communications, 59 (6). pp. 716-719. ISSN 1359-7345. (doi:10.1039/D2CC06060D) (KAR id:99150)
|
PDF
Author's Accepted Manuscript
Language: English |
|
|
Download this file (PDF/2MB) |
Preview |
| Request a format suitable for use with assistive technology e.g. a screenreader | |
| Official URL: https://doi.org/10.1039/D2CC06060D |
|
Abstract
The Cl– diadduct [nBu4N]2[A·2Cl] of the mixed cyclohexatetrelane (SiCl2)5(GeMe2), A, is accessible from Me2GeCl2, 6 eq. Si2Cl6, and 2 eq. [nBu4N]Cl in one step (96%). Free, tenfold functionalized A can be released from the primary product by decomplexation with AlCl3 (78%). Insight into the assembly mechanism of [nBu4N]2[A·2Cl] and the reactivity of A is provided.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/D2CC06060D |
| Uncontrolled keywords: | Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Natural Sciences > Chemistry and Forensic Science |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Chemistry and Forensics
|
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 14 Dec 2022 10:05 UTC |
| Last Modified: | 22 Jul 2025 09:13 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/99150 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
|
|---|---|
| CReDIT Contributor Roles: |
- Link to SensusAccess
- Export to:
- RefWorks
- EPrints3 XML
- BibTeX
- CSV
- Depositors only (login required):
Altmetric
Altmetric
