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A Neutral Beryllium(I) Radical

Czernetzki, Corinna, Arrowsmith, Merle, Fantuzzi, Felipe, Gärtner, Annalena, Tröster, Tobias, Krummenacher, Ivo, Schorr, Fabian, Braunschweig, Holger (2021) A Neutral Beryllium(I) Radical. Angewandte Chemie International Edition, 60 (38). pp. 20776-20780. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202108405) (KAR id:96283)

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Official URL:
https://doi.org/10.1002/anie.202108405

Abstract

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, UV/Vis spectroscopy and X-ray crystallography. DFT calculations show significant spin density at beryllium and confirm donor–acceptor bonding between an alkylberyllium radical fragment and a neutral CAAC ligand.

Item Type: Article
DOI/Identification number: 10.1002/anie.202108405
Uncontrolled keywords: beryllium; cyclic alkyl(amino)carbene; EDA-NOVC; radical; x-ray crystallography
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Felipe Fantuzzi
Date Deposited: 18 Aug 2022 08:27 UTC
Last Modified: 31 Oct 2023 12:42 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/96283 (The current URI for this page, for reference purposes)

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