A Neutral Beryllium(I) Radical

Czernetzki, Corinna, Arrowsmith, Merle, Fantuzzi, Felipe, Gärtner, Annalena, Tröster, Tobias, Krummenacher, Ivo, Schorr, Fabian, Braunschweig, Holger (2021) A Neutral Beryllium(I) Radical. Angewandte Chemie International Edition, 60 (38). pp. 20776-20780. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202108405) (KAR id:96283)

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Official URL: https://doi.org/10.1002/anie.202108405

Abstract

The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, UV/Vis spectroscopy and X-ray crystallography. DFT calculations show significant spin density at beryllium and confirm donor–acceptor bonding between an alkylberyllium radical fragment and a neutral CAAC ligand.

Item Type:	Article
DOI/Identification number:	10.1002/anie.202108405
Uncontrolled keywords:	beryllium; cyclic alkyl(amino)carbene; EDA-NOVC; radical; x-ray crystallography
Subjects:	Q Science > QD Chemistry
Divisions:	Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User:	Felipe Fantuzzi
Date Deposited:	18 Aug 2022 08:27 UTC
Last Modified:	19 Aug 2022 08:32 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/96283 (The current URI for this page, for reference purposes)
Arrowsmith, Merle:	https://orcid.org/0000-0003-1449-5932
Fantuzzi, Felipe:	https://orcid.org/0000-0002-8200-8262
Krummenacher, Ivo:	https://orcid.org/0000-0001-9537-1506
Braunschweig, Holger:	https://orcid.org/0000-0001-9264-1726

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