Czernetzki, Corinna, Arrowsmith, Merle, Fantuzzi, Felipe, Gärtner, Annalena, Tröster, Tobias, Krummenacher, Ivo, Schorr, Fabian, Braunschweig, Holger (2021) A Neutral Beryllium(I) Radical. Angewandte Chemie International Edition, 60 (38). pp. 20776-20780. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202108405) (KAR id:96283)
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| Official URL: https://doi.org/10.1002/anie.202108405 |
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| Resource title: | Ein neutrales Beryllium(I)-Radikal |
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| Resource type: | Publication |
| DOI: | 10.1002/ange.202108405 |
| KDR/KAR URL: | https://kar.kent.ac.uk/98610/ |
| External URL: | https://doi.org/10.1002/ange.202108405 |
Abstract
The reduction of a cyclic alkyl(amino)carbene (CAAC)-stabilized organoberyllium chloride yields the first neutral beryllium radical, which was characterized by EPR, IR, UV/Vis spectroscopy and X-ray crystallography. DFT calculations show significant spin density at beryllium and confirm donor–acceptor bonding between an alkylberyllium radical fragment and a neutral CAAC ligand.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/anie.202108405 |
| Uncontrolled keywords: | beryllium; cyclic alkyl(amino)carbene; EDA-NOVC; radical; x-ray crystallography |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 18 Aug 2022 08:27 UTC |
| Last Modified: | 05 Nov 2024 13:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/96283 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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