Biagini, Stefano C. G., Serpell, Christopher J., birchall, Lee, Shehata, Sara, McCarthy, Sean, Shepherd, Helena Jane, Clark, Ewan R. (2020) Supramolecular behaviour and fluorescence of rhodamine-functionalised ROMP polymers. Polymer Chemistry, 32 (11). pp. 4279-4285. ISSN 1759-9954. (doi:10.1039/D0PY00799D) (KAR id:82135)
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| Official URL: https://doi.org/10.1039/D0PY00799D |
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| Resource title: | DNA intercalation investigation using water soluble fluorophore ROMP polymers |
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| Resource type: | Project |
| : | 78710 |
| KDR/KAR URL: | https://kar.kent.ac.uk/78710/ |
| External URL: |
| Resource title: | Supramolecular Behaviour and Fluorescence of Rhodamine-Functionalised ROMP Polymer |
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| Resource type: | Unpublished paper |
| : | 82210 |
| KDR/KAR URL: | https://kar.kent.ac.uk/82210/ |
| External URL: |
Abstract
Inherently fluorescent polymers are of interest in materials and medicine. We report a ring-opening metathesis polymerisation (ROMP) platform for creation of amphiphilic block copolymers in which one block is formed from rhodamine B-containing monomers. The polymers self-assemble into well-defined micelles which are able to sequester molecular dyes and further interact with them by energy transfer. Despite incorporating a cationic dye known to bind DNA, the polymer micelles do not interact with DNA, indicating that they are potentially safe for use in bioanalytical applications.
| Item Type: | Article |
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| DOI/Identification number: | 10.1039/D0PY00799D |
| Subjects: | Q Science |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Christopher Serpell |
| Date Deposited: | 16 Jul 2020 15:20 UTC |
| Last Modified: | 30 Jan 2023 15:48 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/82135 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Biagini, Stefano C. G..
| Creator's ORCID: |
 https://orcid.org/0000-0002-4713-5127
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| CReDIT Contributor Roles: |
Serpell, Christopher J..
| Creator's ORCID: |
https://orcid.org/0000-0002-2848-9077
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| CReDIT Contributor Roles: |
birchall, Lee.
| Creator's ORCID: | |
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| CReDIT Contributor Roles: |
Shehata, Sara.
| Creator's ORCID: | |
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| CReDIT Contributor Roles: |
Shepherd, Helena Jane.
| Creator's ORCID: |
https://orcid.org/0000-0003-0832-4475
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| CReDIT Contributor Roles: |
Clark, Ewan R..
| Creator's ORCID: |
https://orcid.org/0000-0001-7287-2631
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|---|---|
| CReDIT Contributor Roles: |
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