Birchall, Lee T, Shehata, Sara, McCarthy, Sean, Shepherd, Helena J., Clark, Ewan R., Serpell, C.J., Biagini, Stefano C. G. (2020) Supramolecular Behaviour and Fluorescence of Rhodamine-Functionalised ROMP Polymers. . (Unpublished) (KAR id:82210)
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| Resource title: | DNA intercalation investigation using water soluble fluorophore ROMP polymers |
|---|---|
| Resource type: | Project |
| : | 78710 |
| KDR/KAR URL: | https://kar.kent.ac.uk/78710/ |
| External URL: | |
| Relationship: | IsNewVersionOf |
| Resource title: | Supramolecular behaviour and fluorescence of rhodamine-functionalised ROMP polymers |
|---|---|
| Resource type: | Publication |
| : | 82135 |
| KDR/KAR URL: | https://kar.kent.ac.uk/82135/ |
| External URL: | |
| Relationship: | IsPreviousVersionOf |
Abstract
Inherently fluorescent polymers are of interest in materials and medicine. We report a ring-opening metathesis polymerisation (ROMP) platform for creation of amphiphilic block copolymers in which one block is formed from rhodamine B-containing monomers. The polymers self-assemble into well-defined micelles which are able to sequester molecular dyes and further interact with them by energy transfer. Despite incorporating a cationic dye known to bind DNA, the polymer micelles do not interact with DNA, indicating that they are potentially safe for use in bioanalytical applications.
| Item Type: | Article |
|---|---|
| Uncontrolled keywords: | Supramolecular, Interfacial, and Synthetic Chemistry Group Kent |
| Divisions: | Divisions > Division of Natural Sciences > Biosciences |
| Depositing User: | Stefano Biagini |
| Date Deposited: | 23 Jul 2020 13:49 UTC |
| Last Modified: | 26 Sep 2023 13:45 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/82210 (The current URI for this page, for reference purposes) |
| Shepherd, Helena J.: |
 https://orcid.org/0000-0003-0832-4475
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| Clark, Ewan R.: |
https://orcid.org/0000-0001-7287-2631
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| Serpell, C.J.: |
https://orcid.org/0000-0002-2848-9077
|
| Biagini, Stefano C. G.: |
https://orcid.org/0000-0002-4713-5127
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