Shaves, Chloe L., Villegas‐Escobar, Nery, Clark, Ewan R., Riddlestone, Ian M. (2023) Diverse Cooperative Reactivity at a Square Planar Aluminium Complex and Catalytic Reduction of CO 2. Chemistry – A European Journal, 29 (16). Article Number e202203806. ISSN 1521-3765. (doi:10.1002/chem.202203806) (KAR id:99952)
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| Official URL: https://doi.org/10.1002/chem.202203806 |
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Abstract
The use of a sterically demanding pincer ligand to prepare an unusual square planar aluminium complex is reported. Due to the constrained geometry imposed by the ligand scaffold, this four‐coordinate aluminium centre remains Lewis acidic and reacts via differing metal‐ligand cooperative pathways for activating ketones and CO2. It is also a rare example of a single‐component aluminium system for the catalytic reduction of CO2 to a methanol equivalent at room temperature.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/chem.202203806 |
| Uncontrolled keywords: | aluminium, carbon dioxide, cooperativity, Lewis acid, structural constraint |
| Subjects: |
Q Science Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: | University of Surrey (https://ror.org/00ks66431) |
| SWORD Depositor: | JISC Publications Router |
| Depositing User: | JISC Publications Router |
| Date Deposited: | 08 Feb 2023 14:47 UTC |
| Last Modified: | 05 Nov 2024 13:05 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/99952 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Clark, Ewan R..
| Creator's ORCID: |
 https://orcid.org/0000-0001-7287-2631
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