Rang, Maximilian, Fantuzzi, Felipe, Arrowsmith, Merle, Krummenacher, Ivo, Beck, Eva, Witte, Robert, Matler, Alexander, Rempel, Anna, Bischof, Tobias, Radacki, Krzysztof, and others. (2020) Reduktion und Umlagerung eines Bor(I)-Carbonylkomplexes. Angewandte Chemie, 133 (6). pp. 3000-3005. ISSN 0044-8249. E-ISSN 1521-3757. (doi:10.1002/ange.202014167) (KAR id:98616)
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Language: German 
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| Official URL: https://doi.org/10.1002/ange.202014167 |
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Abstract
Bei der Einelektronenreduktion eines durch eine cyclisches (Alkyl)(amino)carben (CAAC) stabilisierten Arylborylen-Carbonylkomplexes erfolgt die Bildung eines dimeren Borylketyl-Radikalanions, bedingt durch eine intramolekulare Arylmigration zum CO Kohlenstoffatom. Computergestützte Analyse liefert Hinweise auf eine radikalanionische [(CAAC)B(CO)Ar].− Zwischenstufe. Weiterführende Reduktion des entstandenen Komplexes liefert ein hoch nukleophiles (Boranyliden)methanolat.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/ange.202014167 |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Natural Sciences > Chemistry and Forensic Science |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Chemistry and Forensics
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| Funders: |
Deutsche Forschungsgemeinschaft (https://ror.org/018mejw64)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 01 Dec 2022 14:49 UTC |
| Last Modified: | 22 Jul 2025 09:13 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/98616 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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