Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes

Schmidt, Uwe, Fantuzzi, Felipe, Arrowsmith, Merle, Hermann, Alexander, Prieschl, Dominic, Rempel, Anna, Engels, Bernd, Braunschweig, Holger (2020) Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes. Chemical Communications, 56 . pp. 14809-14812. ISSN 1359-7345. (doi:10.1039/D0CC06398C) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:98542)

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Official URL: https://doi.org/10.1039/D0CC06398C

Abstract

Whereas the reduction of N-heterocyclic carbene (NHC)-stabilised cymantrenyldibromoboranes, (NHC)BBr2Cym, in benzene results in the formation of the corresponding diborenes (NHC)2B2Cym2, a change of solvent to THF yields a borylene analogue of the form (NHC)2BCym, stabilised through a boratafulvene/borafulvenium conformation.

Item Type:	Article
DOI/Identification number:	10.1039/D0CC06398C
Divisions:	Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders:	European Research Council (https://ror.org/0472cxd90) Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317)
Depositing User:	Felipe Fantuzzi
Date Deposited:	30 Nov 2022 16:20 UTC
Last Modified:	06 Dec 2022 14:37 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/98542 (The current URI for this page, for reference purposes)
Fantuzzi, Felipe:	https://orcid.org/0000-0002-8200-8262
Arrowsmith, Merle:	https://orcid.org/0000-0003-1449-5932
Engels, Bernd:	https://orcid.org/0000-0003-3057-389X
Braunschweig, Holger:	https://orcid.org/0000-0001-9264-1726

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