Schmidt, Uwe, Fantuzzi, Felipe, Arrowsmith, Merle, Hermann, Alexander, Prieschl, Dominic, Rempel, Anna, Engels, Bernd, Braunschweig, Holger (2020) Tuneable reduction of cymantrenylboranes to diborenes or borylene-derived boratafulvenes. Chemical Communications, 56 . pp. 14809-14812. ISSN 1359-7345. (doi:10.1039/D0CC06398C) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:98542)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication) | |
| Official URL: https://doi.org/10.1039/D0CC06398C |
Abstract
Whereas the reduction of N-heterocyclic carbene (NHC)-stabilised cymantrenyldibromoboranes, (NHC)BBr2Cym, in benzene results in the formation of the corresponding diborenes (NHC)2B2Cym2, a change of solvent to THF yields a borylene analogue of the form (NHC)2BCym, stabilised through a boratafulvene/borafulvenium conformation.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/D0CC06398C |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Funders: |
European Research Council (https://ror.org/0472cxd90)
Coordenação de Aperfeicoamento de Pessoal de Nível Superior (https://ror.org/00x0ma614) Alexander von Humboldt Foundation (https://ror.org/012kf4317) |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 30 Nov 2022 16:20 UTC |
| Last Modified: | 05 Nov 2024 13:03 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/98542 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
|
|---|---|
| CReDIT Contributor Roles: |
- Export to:
- RefWorks
- EPrints3 XML
- BibTeX
- CSV
- Depositors only (login required):
Altmetric
Altmetric
