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A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor

Cui, Jingjing, Weiser, Jonas, Fantuzzi, Felipe, Dietz, Maximilian, Yatsenko, Yelyzaveta, Häfner, Andreas, Nees, Samuel, Krummenacher, Ivo, Zhang, Mingtao, Hammond, Kai, and others. (2022) A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor. Chemical Communications, 58 (96). pp. 13357-13360. ISSN 1364-548X. (doi:10.1039/D2CC05325J) (Access to this publication is currently restricted. You may be able to access a copy if URLs are provided) (KAR id:98290)

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https://doi.org/10.1039/D2CC05325J

Abstract

A bis(germylene) based on a naphthyridine diamine (NDI) is reported. Calculations on the [NDI-Ge2][Fe2(CO)6] complex revealed the six-electron donor behaviour of NDI-Ge2, the first of its kind for bidentate ligands based on group 14 elements.

Item Type: Article
DOI/Identification number: 10.1039/D2CC05325J
Uncontrolled keywords: Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders: National Natural Science Foundation of China (https://ror.org/01h0zpd94)
SWORD Depositor: JISC Publications Router
Depositing User: JISC Publications Router
Date Deposited: 24 Nov 2022 13:53 UTC
Last Modified: 01 Feb 2023 16:32 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/98290 (The current URI for this page, for reference purposes)
Weiser, Jonas: https://orcid.org/0000-0001-6698-2519
Fantuzzi, Felipe: https://orcid.org/0000-0002-8200-8262
Krummenacher, Ivo: https://orcid.org/0000-0001-9537-1506
Zhang, Mingtao: https://orcid.org/0000-0001-9588-9751
Dewhurst, Rian D.: https://orcid.org/0000-0001-5978-811X
Engels, Bernd: https://orcid.org/0000-0003-3057-389X
Braunschweig, Holger: https://orcid.org/0000-0001-9264-1726
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