A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor

Cui, Jingjing, Weiser, Jonas, Fantuzzi, Felipe, Dietz, Maximilian, Yatsenko, Yelyzaveta, Häfner, Andreas, Nees, Samuel, Krummenacher, Ivo, Zhang, Mingtao, Hammond, Kai, and others. (2022) A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor. Chemical Communications, 58 (96). pp. 13357-13360. ISSN 1364-548X. (doi:10.1039/D2CC05325J) (Access to this publication is currently restricted. You may be able to access a copy if URLs are provided) (KAR id:98290)

PDF Author's Accepted Manuscript Language: English Restricted to Repository staff only until 5 November 2023.
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Official URL: https://doi.org/10.1039/D2CC05325J

Abstract

A bis(germylene) based on a naphthyridine diamine (NDI) is reported. Calculations on the [NDI-Ge2][Fe2(CO)6] complex revealed the six-electron donor behaviour of NDI-Ge2, the first of its kind for bidentate ligands based on group 14 elements.

Item Type:	Article
DOI/Identification number:	10.1039/D2CC05325J
Uncontrolled keywords:	Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects:	Q Science > QD Chemistry
Divisions:	Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders:	National Natural Science Foundation of China (https://ror.org/01h0zpd94)
SWORD Depositor:	JISC Publications Router
Depositing User:	JISC Publications Router
Date Deposited:	24 Nov 2022 13:53 UTC
Last Modified:	01 Feb 2023 16:32 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/98290 (The current URI for this page, for reference purposes)
Weiser, Jonas:	https://orcid.org/0000-0001-6698-2519
Fantuzzi, Felipe:	https://orcid.org/0000-0002-8200-8262
Krummenacher, Ivo:	https://orcid.org/0000-0001-9537-1506
Zhang, Mingtao:	https://orcid.org/0000-0001-9588-9751
Dewhurst, Rian D.:	https://orcid.org/0000-0001-5978-811X
Engels, Bernd:	https://orcid.org/0000-0003-3057-389X
Braunschweig, Holger:	https://orcid.org/0000-0001-9264-1726

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