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A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor

Cui, Jingjing, Weiser, Jonas, Fantuzzi, Felipe, Dietz, Maximilian, Yatsenko, Yelyzaveta, Häfner, Andreas, Nees, Samuel, Krummenacher, Ivo, Zhang, Mingtao, Hammond, Kai, and others. (2022) A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor. Chemical Communications, 58 (96). pp. 13357-13360. ISSN 1364-548X. (doi:10.1039/D2CC05325J) (KAR id:98290)

Abstract

A bis(germylene) based on a naphthyridine diamine (NDI) is reported. Calculations on the [NDI-Ge2][Fe2(CO)6] complex revealed the six-electron donor behaviour of NDI-Ge2, the first of its kind for bidentate ligands based on group 14 elements.

Item Type: Article
DOI/Identification number: 10.1039/D2CC05325J
Uncontrolled keywords: Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders: National Natural Science Foundation of China (https://ror.org/01h0zpd94)
SWORD Depositor: JISC Publications Router
Depositing User: JISC Publications Router
Date Deposited: 24 Nov 2022 13:53 UTC
Last Modified: 05 Nov 2023 00:00 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/98290 (The current URI for this page, for reference purposes)

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