A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor

Cui, Jingjing, Weiser, Jonas, Fantuzzi, Felipe, Dietz, Maximilian, Yatsenko, Yelyzaveta, Häfner, Andreas, Nees, Samuel, Krummenacher, Ivo, Zhang, Mingtao, Hammond, Kai, and others. (2022) A rigid redox-active-ligand-supported bis(germylene) as a two-centre six-electron donor. Chemical Communications, 58 (96). pp. 13357-13360. ISSN 1364-548X. (doi:10.1039/D2CC05325J) (KAR id:98290)

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Official URL: https://doi.org/10.1039/D2CC05325J

Abstract

A bis(germylene) based on a naphthyridine diamine (NDI) is reported. Calculations on the [NDI-Ge2][Fe2(CO)6] complex revealed the six-electron donor behaviour of NDI-Ge2, the first of its kind for bidentate ligands based on group 14 elements.

Item Type:	Article
DOI/Identification number:	10.1039/D2CC05325J
Uncontrolled keywords:	Materials Chemistry, Metals and Alloys, Surfaces, Coatings and Films, General Chemistry, Ceramics and Composites, Electronic, Optical and Magnetic Materials, Catalysis
Subjects:	Q Science > QD Chemistry
Institutional Unit:	Schools > School of Natural Sciences > Chemistry and Forensic Science
Former Institutional Unit:	Divisions > Division of Natural Sciences > Chemistry and Forensics
Funders:	National Natural Science Foundation of China (https://ror.org/01h0zpd94)
SWORD Depositor:	JISC Publications Router
Depositing User:	JISC Publications Router
Date Deposited:	24 Nov 2022 13:53 UTC
Last Modified:	22 Jul 2025 09:12 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/98290 (The current URI for this page, for reference purposes)

University of Kent Author Information

Fantuzzi, Felipe.

Creator's ORCID:	https://orcid.org/0000-0002-8200-8262
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