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Reduction and Rearrangement of a Boron(I) Carbonyl Complex

Rang, Maximilian, Fantuzzi, Felipe, Arrowsmith, Merle, Krummenacher, Ivo, Beck, Eva, Witte, Robert, Matler, Alexander, Rempel, Anna, Bischof, Tobias, Radacki, Krzysztof, and others. (2021) Reduction and Rearrangement of a Boron(I) Carbonyl Complex. Angewandte Chemie International Edition, 60 (6). pp. 2963-2968. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202014167) (KAR id:96289)

Abstract

The one-electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)-stabilized arylborylene carbonyl complex yields a dimeric borylketyl radical anion, resulting from an intramolecular aryl migration to the CO carbon atom. Computational analyses support the existence of a [(CAAC)B(CO)Ar].− radical anion intermediate. Further reduction leads to a highly nucleophilic dianionic (boraneylidene)methanolate.

Item Type: Article
DOI/Identification number: 10.1002/anie.202014167
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Felipe Fantuzzi
Date Deposited: 18 Aug 2022 08:55 UTC
Last Modified: 19 Aug 2022 09:06 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/96289 (The current URI for this page, for reference purposes)

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