Rang, Maximilian, Fantuzzi, Felipe, Arrowsmith, Merle, Krummenacher, Ivo, Beck, Eva, Witte, Robert, Matler, Alexander, Rempel, Anna, Bischof, Tobias, Radacki, Krzysztof, and others. (2021) Reduction and Rearrangement of a Boron(I) Carbonyl Complex. Angewandte Chemie International Edition, 60 (6). pp. 2963-2968. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202014167) (KAR id:96289)
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| Official URL: https://doi.org/10.1002/anie.202014167 |
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Abstract
The one-electron reduction of a cyclic (alkyl)(amino)carbene (CAAC)-stabilized arylborylene carbonyl complex yields a dimeric borylketyl radical anion, resulting from an intramolecular aryl migration to the CO carbon atom. Computational analyses support the existence of a [(CAAC)B(CO)Ar].− radical anion intermediate. Further reduction leads to a highly nucleophilic dianionic (boraneylidene)methanolate.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/anie.202014167 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 18 Aug 2022 08:55 UTC |
| Last Modified: | 05 Nov 2024 13:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/96289 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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