Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Hermann, Alexander, Brückner, Tobias, Braunschweig, Holger (2021) Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates. Angewandte Chemie International Edition, 60 (12). pp. 6446-6450. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202015508) (KAR id:96287)
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Language: English 
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| Official URL: https://doi.org/10.1002/anie.202015508 |
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Abstract
Reduction of (CAAC)BBr2(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1002/anie.202015508 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 18 Aug 2022 08:44 UTC |
| Last Modified: | 19 Aug 2022 09:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/96287 (The current URI for this page, for reference purposes) |
| Hagspiel, Stephan: |  https://orcid.org/0000-0002-6049-6007 |
| Arrowsmith, Merle: | https://orcid.org/0000-0003-1449-5932 |
| Fantuzzi, Felipe: | https://orcid.org/0000-0002-8200-8262 |
| Vargas, Alfredo: | https://orcid.org/0000-0001-7491-791X |
| Braunschweig, Holger: | https://orcid.org/0000-0001-9264-1726 |
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