Hagspiel, Stephan, Arrowsmith, Merle, Fantuzzi, Felipe, Vargas, Alfredo, Rempel, Anna, Hermann, Alexander, Brückner, Tobias, Braunschweig, Holger (2021) Highly Colored Boron-Doped Thiazolothiazoles from the Reductive Dimerization of Boron Isothiocyanates. Angewandte Chemie International Edition, 60 (12). pp. 6446-6450. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202015508) (KAR id:96287)
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| Official URL: https://doi.org/10.1002/anie.202015508 |
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Abstract
Reduction of (CAAC)BBr2(NCS) (CAAC=cyclic alkyl(amino)carbene) in the presence of a Lewis base L yields tricoordinate (CAAC)LB(NCS) borylenes which undergo reversible E/Z-isomerization. The same reduction in the absence of L yields deep blue, bis(CAAC)-stabilized, boron-doped, aromatic thiazolothiazoles resulting from the dimerization of dicoordinate (CAAC)B(NCS) borylene intermediates.
| Item Type: | Article |
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| DOI/Identification number: | 10.1002/anie.202015508 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 18 Aug 2022 08:44 UTC |
| Last Modified: | 05 Nov 2024 13:00 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/96287 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Fantuzzi, Felipe.
| Creator's ORCID: |
 https://orcid.org/0000-0002-8200-8262
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