Hagspiel, Stephan, Fantuzzi, Felipe, Dewhurst, Rian D., Gärtner, Annalena, Lindl, Felix, Lamprecht, Anna, Braunschweig, Holger (2021) Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry. Angewandte Chemie International Edition, 60 (24). pp. 13666-13670. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202103521) (KAR id:96285)
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Language: English 
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| Official URL: https://doi.org/10.1002/anie.202103521 |
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Abstract
The first examples of Lewis base adducts of the parent boraphosphaketene (H2B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1002/anie.202103521 |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Chemistry and Forensics |
| Depositing User: | Felipe Fantuzzi |
| Date Deposited: | 18 Aug 2022 08:36 UTC |
| Last Modified: | 19 Aug 2022 08:54 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/96285 (The current URI for this page, for reference purposes) |
| Hagspiel, Stephan: |  https://orcid.org/0000-0002-6049-6007 |
| Fantuzzi, Felipe: | https://orcid.org/0000-0002-8200-8262 |
| Dewhurst, Rian D.: | https://orcid.org/0000-0001-5978-811X |
| Braunschweig, Holger: | https://orcid.org/0000-0001-9264-1726 |
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