Skip to main content
Kent Academic Repository

Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry

Hagspiel, Stephan, Fantuzzi, Felipe, Dewhurst, Rian D., Gärtner, Annalena, Lindl, Felix, Lamprecht, Anna, Braunschweig, Holger (2021) Adducts of the Parent Boraphosphaketene H2BPCO and their Decarbonylative Insertion Chemistry. Angewandte Chemie International Edition, 60 (24). pp. 13666-13670. ISSN 1433-7851. E-ISSN 1521-3773. (doi:10.1002/anie.202103521) (KAR id:96285)

Abstract

The first examples of Lewis base adducts of the parent boraphosphaketene (H2B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B−C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.

Item Type: Article
DOI/Identification number: 10.1002/anie.202103521
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Natural Sciences > Chemistry and Forensics
Depositing User: Felipe Fantuzzi
Date Deposited: 18 Aug 2022 08:36 UTC
Last Modified: 19 Aug 2022 08:54 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/96285 (The current URI for this page, for reference purposes)

University of Kent Author Information

  • Depositors only (login required):

Total unique views for this document in KAR since July 2020. For more details click on the image.