Threshold photoelectron studies of isoxazole over the energy range 9.9-30 eV

Dampc, M., Mielewska, B., Siggel-King, M.R.F., King, G.C., Sivaraman, B., Ptasińska, S., Mason, Nigel, Zubek, M. (2010) Threshold photoelectron studies of isoxazole over the energy range 9.9-30 eV. Chemical Physics, 367 (2-3). pp. 75-79. (doi:10.1016/j.chemphys.2009.10.024) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:74767)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1016/j.chemphys.2009.10.024

Abstract

The threshold photoelectron spectrum of the isoxazole molecule, C3H3NO has been measured over the photon energy range 9.9-30 eV with the use of synchrotron radiation. In the 9.9-10.8 eV range, corresponding to photoionization from the highest occupied molecular orbital 3a″(π3), seven well resolved vibrational series have been observed and their modes are tentatively assigned. A strong adiabatic ionization, with an energy of 11.132 ± 0.003 eV corresponding to the 2a″(π2) band, has also been observed. This is followed by a single vibrational series of the νC-H stretching mode. Photoelectron bands in the energy region 13-30 eV have also been identified, some for the first time.

Item Type:	Article
DOI/Identification number:	10.1016/j.chemphys.2009.10.024
Uncontrolled keywords:	Isoxazole, Photoelectron spectroscopy, Threshold photoionization
Institutional Unit:	Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy
Former Institutional Unit:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Nigel Mason
Date Deposited:	18 Jul 2019 09:25 UTC
Last Modified:	20 May 2025 09:45 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/74767 (The current URI for this page, for reference purposes)

University of Kent Author Information

Mason, Nigel.

Creator's ORCID:	https://orcid.org/0000-0002-4468-8324
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