Dampc, M., Mielewska, B., Siggel-King, M.R.F., King, G.C., Sivaraman, B., Ptasińska, S., Mason, Nigel, Zubek, M. (2010) Threshold photoelectron studies of isoxazole over the energy range 9.9-30 eV. Chemical Physics, 367 (2-3). pp. 75-79. (doi:10.1016/j.chemphys.2009.10.024) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:74767)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: https://doi.org/10.1016/j.chemphys.2009.10.024 |
Abstract
The threshold photoelectron spectrum of the isoxazole molecule, C3H3NO has been measured over the photon energy range 9.9-30 eV with the use of synchrotron radiation. In the 9.9-10.8 eV range, corresponding to photoionization from the highest occupied molecular orbital 3a″(π3), seven well resolved vibrational series have been observed and their modes are tentatively assigned. A strong adiabatic ionization, with an energy of 11.132 ± 0.003 eV corresponding to the 2a″(π2) band, has also been observed. This is followed by a single vibrational series of the νC-H stretching mode. Photoelectron bands in the energy region 13-30 eV have also been identified, some for the first time.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/j.chemphys.2009.10.024 |
| Uncontrolled keywords: | Isoxazole, Photoelectron spectroscopy, Threshold photoionization |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Nigel Mason |
| Date Deposited: | 18 Jul 2019 09:25 UTC |
| Last Modified: | 05 Nov 2024 12:38 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/74767 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Mason, Nigel.
| Creator's ORCID: |
 https://orcid.org/0000-0002-4468-8324
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