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Furnishing Amine-Functionalized Metal–Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification

Gee, William J., Cadman, Laura K., Amer Hamzah, Harina, Mahon, Mary F., Raithby, Paul R., Burrows, Andrew D. (2016) Furnishing Amine-Functionalized Metal–Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification. Inorganic Chemistry, 55 (21). pp. 10839-10842. ISSN 0020-1669. (doi:10.1021/acs.inorgchem.6b01917)

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https://doi.org/10.1021/acs.inorgchem.6b01917

Abstract

The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case, crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.

Item Type: Article
DOI/Identification number: 10.1021/acs.inorgchem.6b01917
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences
Depositing User: William Gee
Date Deposited: 21 May 2019 15:08 UTC
Last Modified: 15 Jan 2020 12:49 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/74029 (The current URI for this page, for reference purposes)
Gee, William J.: https://orcid.org/0000-0002-6520-6216
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