Gee, William J., Cadman, Laura K., Amer Hamzah, Harina, Mahon, Mary F., Raithby, Paul R., Burrows, Andrew D. (2016) Furnishing Amine-Functionalized Metal–Organic Frameworks with the β-Amidoketone Group by Postsynthetic Modification. Inorganic Chemistry, 55 (21). pp. 10839-10842. ISSN 0020-1669. (doi:10.1021/acs.inorgchem.6b01917) (KAR id:74029)
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| Official URL: https://doi.org/10.1021/acs.inorgchem.6b01917 |
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Abstract
The post-synthetic modification (PSM) of amino-functionalized MOFs to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which is both atom-economical and yields high conversions. In each case, crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.
| Item Type: | Article |
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| DOI/Identification number: | 10.1021/acs.inorgchem.6b01917 |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
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| Depositing User: | William Gee |
| Date Deposited: | 21 May 2019 15:08 UTC |
| Last Modified: | 20 May 2025 09:45 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/74029 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Gee, William J..
| Creator's ORCID: |
 https://orcid.org/0000-0002-6520-6216
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