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The influence of stereochemistry on anion binding and transport

Karagiannidis, Louise E., Hiscock, Jennifer R., Gale, Philip A. (2013) The influence of stereochemistry on anion binding and transport. Supramolecular Chemistry, 25 (9-11). pp. 626-630. ISSN 1061-0278. (doi:10.1080/10610278.2013.806809) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1080/10610278.2013.806809

Abstract

Bis(thio)urea receptors (1–4) based on 1,2-bisaminocyclohexane are shown to function as transmembrane anion antiporters. The results show that cis-receptors have a greater propensity for anion transport than analogous trans-receptors. Stability constants using 1H NMR techniques highlight the significance of stereoisomerism on anion binding in solution, as cis-receptors bind anions more strongly than trans-receptors.

Item Type: Article
DOI/Identification number: 10.1080/10610278.2013.806809
Uncontrolled keywords: anion, urea, thiourea, hydrogen bond, stereochemistry
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences
Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Jennifer Hiscock
Date Deposited: 07 Dec 2018 17:13 UTC
Last Modified: 23 Jan 2020 04:15 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/70838 (The current URI for this page, for reference purposes)
Hiscock, Jennifer R.: https://orcid.org/0000-0002-1406-8802
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