The influence of stereochemistry on anion binding and transport

Karagiannidis, Louise E., Hiscock, Jennifer R., Gale, Philip A. (2013) The influence of stereochemistry on anion binding and transport. Supramolecular Chemistry, 25 (9-11). pp. 626-630. ISSN 1061-0278. (doi:10.1080/10610278.2013.806809) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:70838)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1080/10610278.2013.806809

Abstract

Bis(thio)urea receptors (1–4) based on 1,2-bisaminocyclohexane are shown to function as transmembrane anion antiporters. The results show that cis-receptors have a greater propensity for anion transport than analogous trans-receptors. Stability constants using 1H NMR techniques highlight the significance of stereoisomerism on anion binding in solution, as cis-receptors bind anions more strongly than trans-receptors.

Item Type:	Article
DOI/Identification number:	10.1080/10610278.2013.806809
Uncontrolled keywords:	anion, urea, thiourea, hydrogen bond, stereochemistry
Subjects:	Q Science > QD Chemistry
Institutional Unit:	Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy
Former Institutional Unit:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Jennifer Hiscock
Date Deposited:	07 Dec 2018 17:13 UTC
Last Modified:	20 May 2025 09:44 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/70838 (The current URI for this page, for reference purposes)

University of Kent Author Information

Hiscock, Jennifer R..

Creator's ORCID:	https://orcid.org/0000-0002-1406-8802
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