Pearce, Kyle, Borys, Andryj M., Clark, Ewan R., Shepherd, Helena J. (2018) Exploring the reactivity of donor-stabilised phosphenium cations: Lewis acid catalysed reduction of chlorophosphanes by silanes. Inorganic Chemistry, 57 (18). pp. 11530-11536. ISSN 0020-1669. E-ISSN 1520-510X. (doi:10.1021/acs.inorgchem.8b01578) (KAR id:68938)
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Official URL http://dx.doi.org/10.1021/acs.inorgchem.8b01578 |
Abstract
Phosphane-stabilised phosphenium cations react with silanes to effect either reduction to primary or secondary phosphanes, or formation of P-P bonded species depending upon counter-anion. This operates for in situ generated phosphenium cations, allowing catalytic reduction of P(III)-Cl bonds in the absence of strong reducing agents. Anion and substituent dependence studies have allowed insight into the competing mechanisms involved.
Item Type: | Article |
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DOI/Identification number: | 10.1021/acs.inorgchem.8b01578 |
Uncontrolled keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry |
Subjects: | Q Science > QC Physics |
Divisions: | Divisions > Division of Natural Sciences > School of Physical Sciences |
Depositing User: | Ewan Clark |
Date Deposited: | 05 Sep 2018 15:57 UTC |
Last Modified: | 16 Feb 2021 13:57 UTC |
Resource URI: | https://kar.kent.ac.uk/id/eprint/68938 (The current URI for this page, for reference purposes) |
Borys, Andryj M.: | ![]() |
Clark, Ewan R.: | ![]() |
Shepherd, Helena J.: | ![]() |
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