Pearce, Kyle, Borys, Andryj M., Clark, Ewan R., Shepherd, Helena J. (2018) Exploring the reactivity of donor-stabilised phosphenium cations: Lewis acid catalysed reduction of chlorophosphanes by silanes. Inorganic Chemistry, 57 (18). pp. 11530-11536. ISSN 0020-1669. E-ISSN 1520-510X. (doi:10.1021/acs.inorgchem.8b01578) (KAR id:68938)
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| Official URL http://dx.doi.org/10.1021/acs.inorgchem.8b01578 |
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Abstract
Phosphane-stabilised phosphenium cations react with silanes to effect either reduction to primary or secondary phosphanes, or formation of P-P bonded species depending upon counter-anion. This operates for in situ generated phosphenium cations, allowing catalytic reduction of P(III)-Cl bonds in the absence of strong reducing agents. Anion and substituent dependence studies have allowed insight into the competing mechanisms involved.
| Item Type: | Article |
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| DOI/Identification number: | 10.1021/acs.inorgchem.8b01578 |
| Uncontrolled keywords: | Physical and Theoretical Chemistry, Inorganic Chemistry |
| Subjects: | Q Science > QC Physics |
| Divisions: | Divisions > Division of Natural Sciences > School of Physical Sciences |
| Depositing User: | Ewan Clark |
| Date Deposited: | 05 Sep 2018 15:57 UTC |
| Last Modified: | 16 Feb 2021 13:57 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/68938 (The current URI for this page, for reference purposes) |
| Borys, Andryj M.: |  https://orcid.org/0000-0001-8437-2562 |
| Clark, Ewan R.: | https://orcid.org/0000-0001-7287-2631 |
| Shepherd, Helena J.: | https://orcid.org/0000-0003-0832-4475 |
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