Exploring the reactivity of donor-stabilised phosphenium cations: Lewis acid catalysed reduction of chlorophosphanes by silanes

Pearce, Kyle, Borys, Andryj M., Clark, Ewan R., Shepherd, Helena J. (2018) Exploring the reactivity of donor-stabilised phosphenium cations: Lewis acid catalysed reduction of chlorophosphanes by silanes. Inorganic Chemistry, 57 (18). pp. 11530-11536. ISSN 0020-1669. E-ISSN 1520-510X. (doi:10.1021/acs.inorgchem.8b01578) (KAR id:68938)

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Official URL: http://dx.doi.org/10.1021/acs.inorgchem.8b01578

Abstract

Phosphane-stabilised phosphenium cations react with silanes to effect either reduction to primary or secondary phosphanes, or formation of P-P bonded species depending upon counter-anion. This operates for in situ generated phosphenium cations, allowing catalytic reduction of P(III)-Cl bonds in the absence of strong reducing agents. Anion and substituent dependence studies have allowed insight into the competing mechanisms involved.

Item Type:	Article
DOI/Identification number:	10.1021/acs.inorgchem.8b01578
Uncontrolled keywords:	Physical and Theoretical Chemistry, Inorganic Chemistry
Subjects:	Q Science > QC Physics
Divisions:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Ewan Clark
Date Deposited:	05 Sep 2018 15:57 UTC
Last Modified:	09 Dec 2022 06:31 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/68938 (The current URI for this page, for reference purposes)

University of Kent Author Information

Pearce, Kyle.

Creator's ORCID:
CReDIT Contributor Roles:

Borys, Andryj M..

Creator's ORCID:	https://orcid.org/0000-0001-8437-2562
CReDIT Contributor Roles:

Clark, Ewan R..

Creator's ORCID:	https://orcid.org/0000-0001-7287-2631
CReDIT Contributor Roles:

Shepherd, Helena J..

Creator's ORCID:	https://orcid.org/0000-0003-0832-4475
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