Mandal, S., Green, M.A., Natarajan, S. (2004) Synthesis of open-framework iron phosphates, [C5N2H14]2[Fe2IIIF 2(HPO4)4]·2H2O and [C5N2H14][Fe4III(H2O)4F2(PO4)4], with one- and three-dimensional structures. Journal of Solid State Chemistry, 177 (4-5). pp. 1117-1126. ISSN 0022-4596. (doi:10.1016/j.jssc.2003.10.019) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:51126)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/j.jssc.2003.10.019 |
Abstract
The hydrothermal syntheses and structures of two new open-framework iron phosphates, [C5N2H14]2[Fe III 2F2(HPO4)4] ·2H2O, I, and [C5N2H14] [FeIII 4(H2O)4F2(PO 4)4], II, are presented. While the structure of I consist of FeO4F2 octahedra and HPO4 terahedra linked to form one-dimensional structure, that of II consist of FeO4(H 2O)2, FeO4(H2O)F, FeO 4F2 and PO4 units connected to give rise to a three-dimensional structure. The structure of I resembles the naturally occurring mineral tancoite while II resembles the iron phosphate, ULM-12, [C6N2H14][Fe4(PO4) 2F2(H2O)3]. Magnetic susceptibility studies indicate anti-ferromagnetic behavior in both the compounds with T N=200 and 175K for I and II, respectively. Crystal data: I, monoclinic, space group=P21/n (no. 14). a=7.2261(6), b=16.5731(14), c=11.0847(10)Ã?, β=97.265(2)°, V=1316.8(2)Ã?3, Z=4, Ï?calc=1.952gcm-1, μ(MoKα)=1. 446mm-1, R1=0.0448 and wR2=0.1141 for 1882 data [I>2Ï?(I)]; for II, monoclinic, space group=P21/n (no. 14). a=9.9691(3), b=12.4013(3), c=17.3410(3)Ã?, β=103.762(1)°, V=2082.32(9)Ã?3, Z=4, Ï?calc=2.576gcm -1, μ(MoKα)=3.162mm-1, R 1=0.0510 and wR2=0.1064 for 2979 data [I>2Ï?(I)]. © 2003 Elsevier Inc. All rights reserved.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/j.jssc.2003.10.019 |
| Additional information: | Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - J. Solid State Chem. [Field not mapped to EPrints] AD - Framework Solids Laboratory, Chem. and Physics of Materials Unit, Jawaharlal Nehru Ctr. Adv. Sci. Res., Bangalore 560 064, India [Field not mapped to EPrints] AD - Davy-Faraday Research Laboratory, Royal Institution of Great Britain, 21 Albemarle Street, London W1S 4BS, United Kingdom [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints] |
| Uncontrolled keywords: | Anti-ferromagnetic, Hydrothermal synthesis, Iron phosphates, Antiferromagnetism, Crystal structure, Ferromagnetism, Hydrothermal synthesis, Magnetic susceptibility, Minerals, Phosphates, Space groups, Iron compounds, ferric phosphate, article, chemical modification, chemical reaction kinetics, crystal, crystal structure, magnetism |
| Subjects: |
Q Science > QC Physics > QC173.45 Condensed Matter Q Science > QD Chemistry > QD478 Solid State Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Giles Tarver |
| Date Deposited: | 21 Oct 2015 15:14 UTC |
| Last Modified: | 16 Nov 2021 10:21 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/51126 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Green, M.A..
| Creator's ORCID: |
 https://orcid.org/0000-0002-7886-6205
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