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Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato](pyridine)zinc(II)

Went, Michael J., Blower, Philip J., Tocher, Derek, Brown, Oliver (2015) Crystal structure of [butane-2,3-dione bis(4-methylthiosemicarbazonato](pyridine)zinc(II). Acta Crystallographica Section E: Crystallographic Communications, E71 (11). pp. 1349-1351. ISSN 2056-9890. (doi:10.1107/S2056989015019234) (KAR id:51083)

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In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the ZnII ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis­(thio­semicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N-H...N and N-H...S hydrogen-bonding interactions extend parallel to [10-1].

Item Type: Article
DOI/Identification number: 10.1107/S2056989015019234
Additional information: Full text upload complies with journal regulations
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Michael J Went
Date Deposited: 19 Oct 2015 14:53 UTC
Last Modified: 29 May 2019 16:10 UTC
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