Skip to main content

A symmetry-breaking spin-state transition in iron(III)

Griffin, M., Shakespeare, S., Shepherd, H.J., Harding, C.J., Létard, J.-F., Desplanches, C., Goeta, A.E., Howard, J.A.K., Powell, A.K., Mereacre, V., and others. (2011) A symmetry-breaking spin-state transition in iron(III). Angewandte Chemie - International Edition, 50 (4). pp. 896-900. ISSN 14337851 (ISSN). E-ISSN 1521-3773. (doi:10.1002/anie.201005545) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1002/anie.201005545

Abstract

Stepping up: A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe III. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
DOI/Identification number: 10.1002/anie.201005545
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] C2 - 21246686 [Field not mapped to EPrints] AD - Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland [Field not mapped to EPrints] AD - Department of Chemistry, University of Durham (UK), United Kingdom [Field not mapped to EPrints] AD - CNRS, Université de Bordeaux, ICMCB, Pessac, France [Field not mapped to EPrints] AD - Department of Chemistry, Open University, Walton Hall, United Kingdom [Field not mapped to EPrints] AD - Institut für Anorganische Chemie, Karlsruhe Institut für Technologie (KIT), Germany [Field not mapped to EPrints] AD - Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, Belgium [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: iron, magnetism, phase transitions, spin crossover, symmetry breaking, Hysteretic transition, Intermediate phase, Magnetic spin, Spin crossovers, Spin state transition, Structural phase transition, Symmetry-breaking, Unit cells, Iron compounds, Phase transitions, ferric ion, article, chemical structure, chemistry, quantum theory, Raman spectrometry, Ferric Compounds, Molecular Structure, Quantum Theory, Spectrum Analysis, Raman
Subjects: Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 22 Oct 2015 08:46 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50837 (The current URI for this page, for reference purposes)
Shepherd, H.J.: https://orcid.org/0000-0003-0832-4475
  • Depositors only (login required):