A symmetry-breaking spin-state transition in iron(III)

Griffin, M., Shakespeare, S., Shepherd, H.J., Harding, C.J., LÃ©tard, J.-F., Desplanches, C., Goeta, A.E., Howard, J.A.K., Powell, A.K., Mereacre, V., and others. (2011) A symmetry-breaking spin-state transition in iron(III). Angewandte Chemie - International Edition, 50 (4). pp. 896-900. ISSN 14337851 (ISSN). E-ISSN 1521-3773. (doi:10.1002/anie.201005545) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:50837)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1002/anie.201005545

Abstract

Stepping up: A two-step magnetic spin transition with accompanying structural phase transitions is reported for the first time for Fe III. The transitions are observed at 187 K and 90 K on cooling with a hysteretic transition recorded upon heating during the first crossover at 106 K. The intermediate phase persists over 97 K and contains an unprecedented [HS-HS-LS] motif with tripling of the unit cell. Â© 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type:	Article
DOI/Identification number:	10.1002/anie.201005545
Additional information:	Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] C2 - 21246686 [Field not mapped to EPrints] AD - Centre for Synthesis and Chemical Biology, School of Chemistry and Chemical Biology, University College Dublin, Belfield, Dublin 4, Ireland [Field not mapped to EPrints] AD - Department of Chemistry, University of Durham (UK), United Kingdom [Field not mapped to EPrints] AD - CNRS, UniversitÃ© de Bordeaux, ICMCB, Pessac, France [Field not mapped to EPrints] AD - Department of Chemistry, Open University, Walton Hall, United Kingdom [Field not mapped to EPrints] AD - Institut fÃ¼r Anorganische Chemie, Karlsruhe Institut fÃ¼r Technologie (KIT), Germany [Field not mapped to EPrints] AD - Institute of Condensed Matter and Nanosciences, UniversitÃ© Catholique de Louvain, Belgium [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords:	iron, magnetism, phase transitions, spin crossover, symmetry breaking, Hysteretic transition, Intermediate phase, Magnetic spin, Spin crossovers, Spin state transition, Structural phase transition, Symmetry-breaking, Unit cells, Iron compounds, Phase transitions, ferric ion, article, chemical structure, chemistry, quantum theory, Raman spectrometry, Ferric Compounds, Molecular Structure, Quantum Theory, Spectrum Analysis, Raman
Subjects:	Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Giles Tarver
Date Deposited:	22 Oct 2015 08:46 UTC
Last Modified:	05 Nov 2024 10:36 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/50837 (The current URI for this page, for reference purposes)

University of Kent Author Information

Shepherd, H.J..

Creator's ORCID:	https://orcid.org/0000-0003-0832-4475
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