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Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp) 2(NCS) 2]·py

Shepherd, H.J., Palamarciuc, T., Rosa, P., Guionneau, P., Molnár, G., Létard, J.-F., Bousseksou, A. (2012) Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp) 2(NCS) 2]·py. Angewandte Chemie - International Edition, 51 (16). pp. 3910-3914. ISSN 14337851 (ISSN). E-ISSN 1521-3773. (doi:10.1002/anie.201108919) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
https://doi.org/10.1002/anie.201108919

Abstract

A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp) 2(NCS) 2]·py (see picture; dpp=dipyrido[3,2-a:2�3�-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type: Article
DOI/Identification number: 10.1002/anie.201108919
Additional information: Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] AD - Laboratoire de Chimie de Coordination, CNRS UPR-8241, France [Field not mapped to EPrints] AD - Université de Toulouse, UPS, INP, Toulouse, France [Field not mapped to EPrints] AD - CNRS, ICMCB, UPR 9048, 33600 Pessac, France [Field not mapped to EPrints] AD - Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac, France [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords: iron, mechanical properties, molecular materials, N ligands, spin crossover, Linear compression, Low-spin transition, Molecular materials, N ligands, Spin crossovers, Iron, Mechanical properties, Organic polymers
Subjects: Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 22 Oct 2015 08:16 UTC
Last Modified: 23 Jan 2020 04:10 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/50828 (The current URI for this page, for reference purposes)
Shepherd, H.J.: https://orcid.org/0000-0003-0832-4475
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