Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp) 2(NCS) 2]Â·py

Shepherd, H.J., Palamarciuc, T., Rosa, P., Guionneau, P., MolnÃ¡r, G., LÃ©tard, J.-F., Bousseksou, A. (2012) Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp) 2(NCS) 2]Â·py. Angewandte Chemie - International Edition, 51 (16). pp. 3910-3914. ISSN 14337851 (ISSN). E-ISSN 1521-3773. (doi:10.1002/anie.201108919) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:50828)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: https://doi.org/10.1002/anie.201108919

Abstract

A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp) 2(NCS) 2]Â·py (see picture; dpp=dipyrido[3,2-a:2â?²3â?²-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure. Copyright Â© 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Item Type:	Article
DOI/Identification number:	10.1002/anie.201108919
Additional information:	Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Angew. Chem. Int. Ed. [Field not mapped to EPrints] AD - Laboratoire de Chimie de Coordination, CNRS UPR-8241, France [Field not mapped to EPrints] AD - UniversitÃ© de Toulouse, UPS, INP, Toulouse, France [Field not mapped to EPrints] AD - CNRS, ICMCB, UPR 9048, 33600 Pessac, France [Field not mapped to EPrints] AD - Univ. Bordeaux, ICMCB, UPR 9048, 33600 Pessac, France [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints]
Uncontrolled keywords:	iron, mechanical properties, molecular materials, N ligands, spin crossover, Linear compression, Low-spin transition, Molecular materials, N ligands, Spin crossovers, Iron, Mechanical properties, Organic polymers
Subjects:	Q Science > QD Chemistry > QD473 Physical properties in relation to structure
Institutional Unit:	Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy
Former Institutional Unit:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Giles Tarver
Date Deposited:	22 Oct 2015 08:16 UTC
Last Modified:	20 May 2025 09:40 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/50828 (The current URI for this page, for reference purposes)

University of Kent Author Information

Shepherd, H.J..

Creator's ORCID:	https://orcid.org/0000-0003-0832-4475
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