Saines, P.J., Kennedy, B.J. (2006) Implications of the solubility of trivalent lanthanides in A Al2 O4 (A=Ca, Sr, and Ba) for their role in phosphors. Powder Diffraction, 21 (4). pp. 285-288. ISSN 08857156 (ISSN). (doi:10.1154/1.2358362) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:50746)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://www.scopus.com/inward/record.url?eid=2-s2.0... |
Abstract
The technique of standard addition in combination with powder X-ray diffraction was used to identify and quantify the amount of Ln3+ segregating into secondary phases from Ln3+ doped alkaline earth aluminates. Results indicate that Ln3+ ions are more soluble in Ca Al2 O4 than Sr Al2 O4 and Ba Al2 O4, with this being rationalized by the structural details of the A sites. These results indicate that the enhancement of the luminescence afterglow obtained by doping A Al2 O4: Eu2+ samples with Ln3+ ions is a result of much lower doping levels than previously thought. © International Centre for Diffraction Data.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1154/1.2358362 |
| Additional information: | Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Powder Diffr. [Field not mapped to EPrints] AD - School of Chemistry, University of Sydney, Sydney, NSW 2006, Australia [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints] |
| Uncontrolled keywords: | Alkaline-earth aluminates, Lanthanides, Powder X-ray diffraction, Quantitative analysis, Standard addition, Alkaline earth, Alkaline earth aluminates, Doping levels, Powder X ray diffraction, Secondary phasis, Standard addition, Structural details, Trivalent lanthanides, Aluminum compounds, Calcium, Chemical analysis, X ray diffraction, Rare earth elements |
| Subjects: |
Q Science > QC Physics > QC173.45 Condensed Matter Q Science > QD Chemistry > QD478 Solid State Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Paul Saines |
| Date Deposited: | 07 Oct 2015 10:27 UTC |
| Last Modified: | 05 Nov 2024 10:36 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/50746 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Saines, P.J..
| Creator's ORCID: |
 https://orcid.org/0000-0002-4207-2112
|
|---|---|
| CReDIT Contributor Roles: |
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