Thorogood, G.J., Saines, P.J., Kennedy, B.J., Withers, R.L., Elcombe, M.M. (2008) Diffuse scattering in the cesium pyrochlore CsTi0.5W1.5O6. Materials Research Bulletin, 43 (4). pp. 787-795. ISSN 00255408 (ISSN). (doi:10.1016/j.materresbull.2007.12.017) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:50740)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://www.scopus.com/inward/record.url?eid=2-s2.0... |
|
Abstract
The structure of the defect pyrochlore CsTi0.5W1.5O6 has been investigated using electron, synchrotron X-ray and neutron diffraction methods. The material is cubic a = 10.2773 Ã? with displacive disorder of the Cs cations along the ã??1 1 1ã?? direction. The local structure, revealed by the diffuse structure in the electron diffraction patterns shows there is correlated displacement of the heavy Cs atoms along the ã??1 1 0ã?? directions. The thermal expansion of the material is also described. © 2008 Elsevier Ltd. All rights reserved.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/j.materresbull.2007.12.017 |
| Additional information: | Unmapped bibliographic data: LA - English [Field not mapped to EPrints] J2 - Mater Res Bull [Field not mapped to EPrints] AD - Institute of Materials and Engineering Science, Australian Nuclear Science and Technology Organisation, Private Mail Bag 1, Menai, NSW 2234, Australia [Field not mapped to EPrints] AD - School of Chemistry, The University of Sydney, Sydney, NSW 2006, Australia [Field not mapped to EPrints] AD - Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia [Field not mapped to EPrints] AD - Bragg Institute, Australian Nuclear Science and Technology Organisation, Private Mail Bag 1, Menai, NSW 2234, Australia [Field not mapped to EPrints] DB - Scopus [Field not mapped to EPrints] |
| Uncontrolled keywords: | A. Oxides, C. Electron diffraction, C. Neutron scattering, C. X-ray diffraction, D. Thermal expansion, Defects, Diffraction patterns, Diffusion, Neutron diffraction, Synchrotron radiation, Thermal expansion, X ray diffraction, Diffuse scattering, Diffuse structure, Pyrochlore, Cesium compounds |
| Subjects: |
Q Science > QC Physics > QC173.45 Condensed Matter REF2014 Units of Assessment > Main panel C > C19 Business and Management Studies > QC173.45 Condensed Matter Q Science > QD Chemistry > QD478 Solid State Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
|
| Depositing User: | Paul Saines |
| Date Deposited: | 07 Oct 2015 10:20 UTC |
| Last Modified: | 20 May 2025 09:40 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/50740 (The current URI for this page, for reference purposes) |
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https://orcid.org/0000-0002-4207-2112
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