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E-H (E = R3Si or H) bond activation by B(C6F 5)3 and heteroarenes; Competitive dehydrosilylation, hydrosilylation and hydrogenation

Curless, Liam D., Clark, Ewan R., Dunsford, Jay J., Ingleson, Michael J. (2013) E-H (E = R3Si or H) bond activation by B(C6F 5)3 and heteroarenes; Competitive dehydrosilylation, hydrosilylation and hydrogenation. Chemical Communications, 50 (40). pp. 5270-5272. ISSN 1359-7345. (doi:10.1039/c3cc47372d) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://www.dx.doi.org/10.1039/c3cc47372d

Abstract

In the presence of B(C6F5)3 five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H2 as a by-product making the process catalytic in B(C6F5) 3 but also enabling competitive heteroarene hydrogenation. © the Partner Organisations 2014.

Item Type: Article
DOI/Identification number: 10.1039/c3cc47372d
Uncontrolled keywords: heteroarene derivative, polycyclic aromatic hydrocarbon, silane derivative, unclassified drug, article, catalysis, chemical bond, chemical modification, chemical structure, dehydrosilylation, hydrogenation, hydrosilylation, stoichiometry
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 29 Jul 2015 15:07 UTC
Last Modified: 29 May 2019 14:56 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49869 (The current URI for this page, for reference purposes)
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