Curless, Liam D., Clark, Ewan R., Dunsford, Jay J., Ingleson, Michael J. (2013) E-H (E = R3Si or H) bond activation by B(C6F 5)3 and heteroarenes; Competitive dehydrosilylation, hydrosilylation and hydrogenation. Chemical Communications, 50 (40). pp. 5270-5272. ISSN 1359-7345. (doi:10.1039/c3cc47372d) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:49869)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://www.dx.doi.org/10.1039/c3cc47372d |
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| Additional URLs: |
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Abstract
In the presence of B(C6F5)3 five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H2 as a by-product making the process catalytic in B(C6F5) 3 but also enabling competitive heteroarene hydrogenation. © the Partner Organisations 2014.
| Item Type: | Article |
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| DOI/Identification number: | 10.1039/c3cc47372d |
| Uncontrolled keywords: | heteroarene derivative, polycyclic aromatic hydrocarbon, silane derivative, unclassified drug, article, catalysis, chemical bond, chemical modification, chemical structure, dehydrosilylation, hydrogenation, hydrosilylation, stoichiometry |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
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| Depositing User: | Giles Tarver |
| Date Deposited: | 29 Jul 2015 15:07 UTC |
| Last Modified: | 20 May 2025 09:39 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/49869 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Clark, Ewan R..
| Creator's ORCID: |
 https://orcid.org/0000-0001-7287-2631
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