Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles

Clark, Ewan R., Hayward, John J., Leontowicz, Bryce J., Anwar, Muhammad U., Pilkington, Melanie, Rawson, Jeremy M. (2015) Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles. Dalton Transactions, 44 (5). pp. 2071-2074. ISSN 1477-9226. (doi:10.1039/c4dt03467h) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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http://www.dx.doi.org/10.1039/c4dt03467h

Abstract

CuII-promoted aerial oxidation of a series of benzothiadiazines (1) under ambient conditions affords the first structurally characterised examples of thiadiazine S-oxides (2). The isolation of the homoleptic CuII 3-(2?-pyridyl)benzothiadiazide-S-oxide complex provides insight into the reaction mechanism.

Item Type: Article
DOI/Identification number: 10.1039/c4dt03467h
Uncontrolled keywords: Aerial oxidation, Ambient conditions, Heterocycles, Homoleptic, Pyridyl, Reaction mechanism, S oxides, Inorganic compounds
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Physical Sciences > Functional Materials Group
Depositing User: Giles Tarver
Date Deposited: 29 Jul 2015 15:01 UTC
Last Modified: 29 May 2019 14:56 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/49867 (The current URI for this page, for reference purposes)
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