Clark, Ewan R., Hayward, John J., Leontowicz, Bryce J., Anwar, Muhammad U., Pilkington, Melanie, Rawson, Jeremy M. (2015) Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles. Dalton Transactions, 44 (5). pp. 2071-2074. ISSN 1477-9226. (doi:10.1039/c4dt03467h) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:49867)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://www.dx.doi.org/10.1039/c4dt03467h |
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| Additional URLs: |
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Abstract
CuII-promoted aerial oxidation of a series of benzothiadiazines (1) under ambient conditions affords the first structurally characterised examples of thiadiazine S-oxides (2). The isolation of the homoleptic CuII 3-(2?-pyridyl)benzothiadiazide-S-oxide complex provides insight into the reaction mechanism.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/c4dt03467h |
| Uncontrolled keywords: | Aerial oxidation, Ambient conditions, Heterocycles, Homoleptic, Pyridyl, Reaction mechanism, S oxides, Inorganic compounds |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
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| Depositing User: | Giles Tarver |
| Date Deposited: | 29 Jul 2015 15:01 UTC |
| Last Modified: | 20 May 2025 09:39 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/49867 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Clark, Ewan R..
| Creator's ORCID: |
 https://orcid.org/0000-0001-7287-2631
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