Complete reductive cleavage of CO facilitated by highly electrophilic borocations

Curless, Liam D., Clark, Ewan R., Cid, Jessica, Del Grosso, Alessandro, Ingleson, Michael J. (2015) Complete reductive cleavage of CO facilitated by highly electrophilic borocations. Chemical Communications, 51 (54). pp. 10903-10906. ISSN 1359-7345. (doi:10.1039/c5cc03504j) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:49865)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL: http://www.dx.doi.org/10.1039/c5cc03504j
Additional URLs: http://www.scopus.com/inward/record.url?...

Abstract

The addition of CO to [((R3N)BH2)2(?-H)][B(C6F5)4] leads to formation of trimethylboroxine ((MeBO)3) and [(R3N)2BH2][B(C6F5)4]. When R = Et, [(Et3N)H2B(?-O)B(CH3)NEt3][B(C6F5)4], is isolated and demonstrated to be an intermediate in the formation of (MeBO)3. © 2015 The Royal Society of Chemistry.

Item Type:	Article
DOI/Identification number:	10.1039/c5cc03504j
Uncontrolled keywords:	amine, borane derivative, boron, carbon monoxide, Lewis acid, trimethylboroxine, unclassified drug, Article, electrophilicity, nuclear magnetic resonance spectroscopy, nucleophilicity, proton nuclear magnetic resonance, solid state, X ray diffraction
Subjects:	Q Science > QD Chemistry
Institutional Unit:	Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy
Former Institutional Unit:	Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User:	Giles Tarver
Date Deposited:	29 Jul 2015 13:55 UTC
Last Modified:	20 May 2025 09:39 UTC
Resource URI:	https://kar.kent.ac.uk/id/eprint/49865 (The current URI for this page, for reference purposes)

University of Kent Author Information

Clark, Ewan R..

Creator's ORCID:	https://orcid.org/0000-0001-7287-2631
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