Curless, Liam D., Clark, Ewan R., Cid, Jessica, Del Grosso, Alessandro, Ingleson, Michael J. (2015) Complete reductive cleavage of CO facilitated by highly electrophilic borocations. Chemical Communications, 51 (54). pp. 10903-10906. ISSN 1359-7345. (doi:10.1039/c5cc03504j) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:49865)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://www.dx.doi.org/10.1039/c5cc03504j |
Abstract
The addition of CO to [((R3N)BH2)2(?-H)][B(C6F5)4] leads to formation of trimethylboroxine ((MeBO)3) and [(R3N)2BH2][B(C6F5)4]. When R = Et, [(Et3N)H2B(?-O)B(CH3)NEt3][B(C6F5)4], is isolated and demonstrated to be an intermediate in the formation of (MeBO)3. © 2015 The Royal Society of Chemistry.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/c5cc03504j |
| Uncontrolled keywords: | amine, borane derivative, boron, carbon monoxide, Lewis acid, trimethylboroxine, unclassified drug, Article, electrophilicity, nuclear magnetic resonance spectroscopy, nucleophilicity, proton nuclear magnetic resonance, solid state, X ray diffraction |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | Giles Tarver |
| Date Deposited: | 29 Jul 2015 13:55 UTC |
| Last Modified: | 05 Nov 2024 10:34 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/49865 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Clark, Ewan R..
| Creator's ORCID: |
 https://orcid.org/0000-0001-7287-2631
|
|---|---|
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