Cao, G., Concas, G., Corrias, A., Orru', R., Paschina, G., Simoncini, B., Spano, G. (1997) Investigation of the Reaction between Fe2O3 and Al Accomplished by Ball Milling and Self-Propagating High-Temperature Techniques. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 52 (6-7). pp. 539-549. ISSN 0932-0784. (doi:10.1515/zna-1997-6-713) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:46234)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://zfn.mpdl.mpg.de/data/Reihe_A/52/ZNA-1997-52... |
|
Abstract
In this work we investigate the mechanism of product formation of the aluminothermic reaction of Fe2O3 in the presence of Al2O3 using Ball Milling and Self-propagating High-temperature techniques. Results obtained by experiments under either argon or air atmosphere are analysed by X-ray diffraction and Mössbauer spectroscopy, together with microstructure observations. It is shown that ball milling products are strongly affected by the kind of atmosphere, while self-propagating high-temperature ones are only weakly influenced. Reaction mechanisms taking place in these cases are proposed. While ball milling involves only solid state reactions, the formation of a melt occurs under self-propagating high-temperature conditions.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1515/zna-1997-6-713 |
| Uncontrolled keywords: | Aluminothermic reduction, Ball Milling, Mechanism of reaction, Mössbauer spectroscopy, Self-propagating High-temperature Synthesis, X-ray diffraction |
| Subjects: | Q Science > QC Physics > QC176.8.N35 Nanoscience, nanotechnology |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
|
| Depositing User: | Anna Corrias |
| Date Deposited: | 17 Dec 2014 12:34 UTC |
| Last Modified: | 20 May 2025 09:35 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/46234 (The current URI for this page, for reference purposes) |
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https://orcid.org/0000-0002-5190-8196
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