Sowrey, Frank E., Blower, Philip J., Jeffery, John C., MacLean, Elizabeth J., Went, Michael J. (2002) The effect of substitution of a thioether donor by a phosphine donor in thiacrown complexes of iron. Inorganic Chemistry Communications, 5 (10). pp. 832-836. ISSN 1387-7003. (doi:10.1016/S1387-7003(02)00585-3) (KAR id:3756)
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Official URL: http://dx.doi.org/10.1016/S1387-7003(02)00585-3 |
Abstract
Electrospray mass spectrometry and thermogravimetric analysis reveals that bis(1-phenyl-1-phospha-4,7-dithiacyclononane)iron(II) is more susceptible to ethene loss than bis(1,4,7-trithiacyclononane)iron(II). This is in accord with X-ray crystallographic studies, which show that the C-S bonds are longer in the former complex suggesting an increased population of the C-S sigma* pi-acceptor orbitals.
Item Type: | Article |
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DOI/Identification number: | 10.1016/S1387-7003(02)00585-3 |
Uncontrolled keywords: | bond cleavage; thioether; phosphine; iron complexes; macrocycle |
Subjects: | Q Science > QD Chemistry |
Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
Depositing User: | Michael Went |
Date Deposited: | 11 Jun 2008 17:05 UTC |
Last Modified: | 16 Nov 2021 09:42 UTC |
Resource URI: | https://kar.kent.ac.uk/id/eprint/3756 (The current URI for this page, for reference purposes) |
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