Sowrey, Frank E., Blower, Philip J., Jeffery, John C., MacLean, Elizabeth J., Went, Michael J. (2002) The effect of substitution of a thioether donor by a phosphine donor in thiacrown complexes of iron. Inorganic Chemistry Communications, 5 (10). pp. 832-836. ISSN 1387-7003. (doi:10.1016/S1387-7003(02)00585-3) (KAR id:3756)
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| Official URL: http://dx.doi.org/10.1016/S1387-7003(02)00585-3 |
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Abstract
Electrospray mass spectrometry and thermogravimetric analysis reveals that bis(1-phenyl-1-phospha-4,7-dithiacyclononane)iron(II) is more susceptible to ethene loss than bis(1,4,7-trithiacyclononane)iron(II). This is in accord with X-ray crystallographic studies, which show that the C-S bonds are longer in the former complex suggesting an increased population of the C-S sigma* pi-acceptor orbitals.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/S1387-7003(02)00585-3 |
| Uncontrolled keywords: | bond cleavage; thioether; phosphine; iron complexes; macrocycle |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
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| Depositing User: | Michael Went |
| Date Deposited: | 11 Jun 2008 17:05 UTC |
| Last Modified: | 20 May 2025 09:29 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/3756 (The current URI for this page, for reference purposes) |
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