Holder, Simon J., Elemans, Johannes A. A. W., Donners, J.M., Boerakker, Mark J., de Gelder, R., Barbera, J., Rowan, Alan E., Nolte, Roeland J.M. (2001) Lamellar organic thin films through self-assembly and molecular recognition. Journal of Organic Chemistry, 66 (2). pp. 391-399. ISSN 0022-3263. (doi:10.1021/jo0008035) (KAR id:2547)
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| Official URL: https://doi.org/10.1021/jo0008035 |
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Abstract
Molecular clips possessing U-shaped cavities have been functionalized on their convex side with long aliphatic tails. These molecules form dimers which self-assemble into malleable lamellar thin films. Upon addition of a guest (methyl 3,5-dihydroxybenzoate), a 1:1 host-guest complex is formed, which prohibits clip dimerization. As a result, the lamellar structure of the material is lost. Complexation of 3,5-dihydroxybenzoic acid in the clip results in host-guest complexes which dimerize by hydrogen bonding interactions between the carboxylic acid functions of the bound guests. This dimerization restores the lamellar type architecture of the material.
| Item Type: | Article |
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| DOI/Identification number: | 10.1021/jo0008035 |
| Additional information: | 34 AMER CHEMICAL SOC |
| Uncontrolled keywords: | HYDROGEN-BONDED NETWORKS; BINDING FEATURES; GUEST-BINDING; CLIPS; NANOSTRUCTURES; CRYSTALS; DIPHENYLGLYCOLURIL; WATER |
| Subjects: | Q Science > QD Chemistry |
| Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
| Former Institutional Unit: |
Divisions > Division of Natural Sciences > Physics and Astronomy
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| Depositing User: | Simon Holder |
| Date Deposited: | 26 Jun 2008 14:39 UTC |
| Last Modified: | 20 May 2025 09:29 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/2547 (The current URI for this page, for reference purposes) |
University of Kent Author Information
Holder, Simon J..
| Creator's ORCID: |
 https://orcid.org/0000-0001-8977-9257
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