Thiel, Roger C., Benfield, Robert E., Zanoni, Roberto, Smit, Huub H. A., Dirken, Mark W. (1993) The physical-properties of the metal cluster compound AU55(PPH3)12CL6. Structure and Bonding, 81 . pp. 1-39. ISSN 0081-5993. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:20714)
The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. |
Abstract
A discussion is given of the thermal, electronic, and magnetic properties of the gold cluster compound Au55(PPh3)12Cl6. These results are combined to form a consistent physical picture of the system. The coordination numbers of the individual gold sites in this cluster compound play an essential role. It is shown, making use of the results of new physical measurements as well as information from the physical and chemical literature, that the gold core of this cluster material already exhibits metallic bonding, while at the same time displaying some of the characteristics of a discrete energy level spectrum.
Item Type: | Article |
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Subjects: |
Q Science > QD Chemistry Q Science > QC Physics |
Institutional Unit: | Schools > School of Engineering, Mathematics and Physics > Physics and Astronomy |
Former Institutional Unit: |
School of Physical Sciences Divisions > Division of Natural Sciences > Physics and Astronomy
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Depositing User: | O.O. Odanye |
Date Deposited: | 20 Jul 2009 20:16 UTC |
Last Modified: | 20 May 2025 09:34 UTC |
Resource URI: | https://kar.kent.ac.uk/id/eprint/20714 (The current URI for this page, for reference purposes) |
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