Thiel, Roger C., Benfield, Robert E., Zanoni, Roberto, Smit, Huub H. A., Dirken, Mark W. (1993) Electronic structure and bonding of the metal cluster compound Au55(PPh3)12Cl6. Zeitschrift für Physik D Atoms, Molecules and Clusters, 26 (1). pp. 162-165. ISSN 0178-7683. E-ISSN 1431-5866. (doi:10.1007/BF01429131) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:20713)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1007/BF01429131 |
Abstract
We discuss the electronic structure, bonding and physical properties of the gold cluster compound Au55(PPh3)12Cl6. Results from our experimental measurements, including EXAFS, specific heat, Mossbauer, UV-visible and photoelectron spectroscopy, are combined with those of other work to form a consistent physical picture of the system. The bonding in Au55(PPh3)12Cl6 is much more delocalised and non-directional than in smaller gold cluster molecules. The Au55 cluster exhibits a substantial degree of metallic bonding, while displaying some of the characteristics of a discrete energy level spectrum.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1007/BF01429131 |
| Subjects: |
Q Science > QD Chemistry Q Science > QC Physics |
| Divisions: | Divisions > Division of Natural Sciences > Physics and Astronomy |
| Depositing User: | O.O. Odanye |
| Date Deposited: | 20 Jul 2009 20:23 UTC |
| Last Modified: | 05 Nov 2024 09:58 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/20713 (The current URI for this page, for reference purposes) |
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