Intramolecular Interactions In Dimethyl 2,2'-Bipyridine-3,3'-Dicarboxylate

Rice, Craig R. and Robinson, Kathryn J. and Wallis, John D. (1993) Intramolecular Interactions In Dimethyl 2,2'-Bipyridine-3,3'-Dicarboxylate. Acta Crystallographica Section C-Crystal Structure Communications, 49 (part 11). pp. 1980-1982. ISSN 0108-2701. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

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The title compound crystallizes from acetone with the pyridine rings arranged at 53 degrees to each other in a trans conformation. There are intramolecular interactions between the alkoxy O atoms of the ester groups and the C2 atoms of the opposite rings, similar to those observed in the 3,3'-dinitro analogue. There are no significant intramolecular interactions between ring N atoms and ester carbonyl C atoms, although similar 1,5 interactions have been observed in other cases.

Item Type: Article
Subjects: Q Science
Divisions: Faculties > Science Technology and Medical Studies > School of Physical Sciences
Depositing User: E.C. Henry-Duru
Date Deposited: 05 Oct 2009 16:47
Last Modified: 17 Jul 2014 09:06
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