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Intramolecular Interactions In Dimethyl 2,2'-Bipyridine-3,3'-Dicarboxylate

Rice, Craig R., Robinson, Kathryn J., Wallis, John D. (1993) Intramolecular Interactions In Dimethyl 2,2'-Bipyridine-3,3'-Dicarboxylate. Acta Crystallographica Section C-Crystal Structure Communications, 49 (part 1). pp. 1980-1982. ISSN 0108-2701. (doi:10.1107/S0108270193005931) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:20619)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL:
http://dx.doi.org/10.1107/S0108270193005931

Abstract

The title compound crystallizes from acetone with the pyridine rings arranged at 53 degrees to each other in a trans conformation. There are intramolecular interactions between the alkoxy O atoms of the ester groups and the C2 atoms of the opposite rings, similar to those observed in the 3,3'-dinitro analogue. There are no significant intramolecular interactions between ring N atoms and ester carbonyl C atoms, although similar 1,5 interactions have been observed in other cases.

Item Type: Article
DOI/Identification number: 10.1107/S0108270193005931
Subjects: Q Science
Divisions: Divisions > Division of Natural Sciences > Physics and Astronomy
Depositing User: E.C. Henry-Duru
Date Deposited: 05 Oct 2009 16:47 UTC
Last Modified: 16 Nov 2021 09:58 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/20619 (The current URI for this page, for reference purposes)

University of Kent Author Information

Wallis, John D..

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