Renfrew, A. Hunter M., Taylor, John A., Whitmore, James M.J., Williams, Andrew (1994) Timing of Bonding Changes IN Fundamental Reactions in Solutions - Pyridinolysis of a Triazinyridinium Salt. Journal of the Chemical Society-Perkin Transactions 2, (12). pp. 2383-2384. ISSN 0300-9580. (doi:10.1039/P29940002383) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:19983)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1039/P29940002383 |
Abstract
Pyridinolysis of 1-(4,6-diphenoxy-1,3,5-triazin-2-yl) pyridinium chloride with substituted pyridines in aqueous solution exhibits a non-linear Bronsted correlation possessing a break-point at the pK(a) of the pyridine nucleophile equal to that of the leaving group: the results are consistent with the intervention of a Meisenheimer-like intermediate and the full effective charge map for solution states along the reaction coordinate indicates substantial bonding change in the formation of the transition states.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1039/P29940002383 |
| Additional information: | Document Type: Note |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Computing, Engineering and Mathematical Sciences > School of Engineering and Digital Arts |
| Depositing User: | P. Ogbuji |
| Date Deposited: | 19 Jun 2009 17:13 UTC |
| Last Modified: | 05 Nov 2024 09:57 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/19983 (The current URI for this page, for reference purposes) |
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