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Timing of Bonding Changes IN Fundamental Reactions in Solutions - Pyridinolysis of a Triazinyridinium Salt

Renfrew, A. Hunter M., Taylor, John A., Whitmore, James M.J., Williams, Andrew (1994) Timing of Bonding Changes IN Fundamental Reactions in Solutions - Pyridinolysis of a Triazinyridinium Salt. Journal of the Chemical Society-Perkin Transactions 2, (12). pp. 2383-2384. ISSN 0300-9580. (doi:10.1039/P29940002383) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:19983)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided.
Official URL:
http://dx.doi.org/10.1039/P29940002383

Abstract

Pyridinolysis of 1-(4,6-diphenoxy-1,3,5-triazin-2-yl) pyridinium chloride with substituted pyridines in aqueous solution exhibits a non-linear Bronsted correlation possessing a break-point at the pK(a) of the pyridine nucleophile equal to that of the leaving group: the results are consistent with the intervention of a Meisenheimer-like intermediate and the full effective charge map for solution states along the reaction coordinate indicates substantial bonding change in the formation of the transition states.

Item Type: Article
DOI/Identification number: 10.1039/P29940002383
Additional information: Document Type: Note
Subjects: Q Science > QD Chemistry
Divisions: Divisions > Division of Computing, Engineering and Mathematical Sciences > School of Engineering and Digital Arts
Depositing User: P. Ogbuji
Date Deposited: 19 Jun 2009 17:13 UTC
Last Modified: 16 Nov 2021 09:58 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/19983 (The current URI for this page, for reference purposes)

University of Kent Author Information

Williams, Andrew.

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