Baxter, Paul N. W., Connor, Joseph A. (1995) Solvatochomsim in Sbstituted 2,2' -Bipyridintetracarbonyl-Metal Complexes of Chromium,Molybdenum and Tugsten. Journal of Organometallic Chemistry, 486 (1-2). pp. 115-121. ISSN 0022-328X. (doi:10.1016/0022-328X(94)05058-J) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided) (KAR id:19695)
| The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. | |
| Official URL: http://dx.doi.org/10.1016/0022-328X(94)05058-J |
Abstract
The influence of various solvents on the electronic absorption spectra in the visible region of complexes of the general type [M(CO)(4)(n,n'-X(2)-bipy)] (M = Cr, Mo, W; n = 3, 4, 5, 6; X = CH3, CN, CO2CH3; bipy = 2,2'-bipyridine) has been measured. Molar absorption coefficients are reported. Attempts to correlate this information with the solvent polarity parameter proposed by Manuta and Lees indicate that the effects of geometric distortion in the substrate complex preclude a simple explanation of the observations in terms of a single parameter.
| Item Type: | Article |
|---|---|
| DOI/Identification number: | 10.1016/0022-328X(94)05058-J |
| Uncontrolled keywords: | CHROMIUM, MOLYBDENUM; TUNGSTEN; SOLVATOCHROMISM; BIPYRIDINE; CARBONYL |
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Divisions > Division of Computing, Engineering and Mathematical Sciences > School of Engineering and Digital Arts |
| Depositing User: | P. Ogbuji |
| Date Deposited: | 08 Jun 2009 15:15 UTC |
| Last Modified: | 05 Nov 2024 09:56 UTC |
| Resource URI: | https://kar.kent.ac.uk/id/eprint/19695 (The current URI for this page, for reference purposes) |
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