Ozturk, Turan and Rice, Craig R. and Wallis, John D. (1995) Synthesis Of A Chiral Monosubstituted Derivative Of Bis(Ethylenedithio)Tetrathiafulvalene - Reaction Of The Cyclic Sulfate Ester Of R,R-1,4-Difluorobutane-2,3-Diol With 2-Thioxo-1,3-Dithiole-4,5-Dithiolate. Journal of Materials Chemistry, 5 (10). pp. 1553-1556. ISSN 0959-9428. (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)
2-Thioxo-1,3-dithiole-4 5-dithiolate reacts stereospecifically with the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol by two nucleophilic attacks, ring opening of the cyclic sulfate ester at carbon and displacement of the nearer fluorine atom, to form a derivative of the 1,3-dithiolo[4,5-b]-1,4-dithiin ring system. This product is converted in two steps into an analogue of bis(ethylenedithio)tetrathiafulvalene with a 2-fluoro-1-hydroxyethyl side-chain, a new substrate for the preparation of electroactive materials.
|Subjects:||Q Science > QD Chemistry|
|Divisions:||Faculties > Science Technology and Medical Studies > School of Biosciences|
|Depositing User:||O.O. Odanye|
|Date Deposited:||01 Jun 2009 19:56|
|Last Modified:||25 Jun 2014 11:30|
|Resource URI:||https://kar.kent.ac.uk/id/eprint/19431 (The current URI for this page, for reference purposes)|