Skip to main content

Synthesis of a chiral monosubstituted derivative of bis(ethylenedithio)tetrathiafulvalene: reaction of the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol with 2-thioxo-1,3-dithiole-4,5-dithiolate

Ozturk, Turan, Rice, Craig R., Wallis, John D. (1995) Synthesis of a chiral monosubstituted derivative of bis(ethylenedithio)tetrathiafulvalene: reaction of the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol with 2-thioxo-1,3-dithiole-4,5-dithiolate. Journal of Materials Chemistry, 5 (10). pp. 1553-1556. ISSN 0959-9428. (doi:10.1039/jm9950501553) (The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided)

The full text of this publication is not currently available from this repository. You may be able to access a copy if URLs are provided. (Contact us about this Publication)
Official URL
http://dx.doi.org/10.1039/jm9950501553

Abstract

2-Thioxo-1,3-dithiole-4 5-dithiolate reacts stereospecifically with the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol by two nucleophilic attacks, ring opening of the cyclic sulfate ester at carbon and displacement of the nearer fluorine atom, to form a derivative of the 1,3-dithiolo[4,5-b]-1,4-dithiin ring system. This product is converted in two steps into an analogue of bis(ethylenedithio)tetrathiafulvalene with a 2-fluoro-1-hydroxyethyl side-chain, a new substrate for the preparation of electroactive materials.

Item Type: Article
DOI/Identification number: 10.1039/jm9950501553
Subjects: Q Science > QD Chemistry
Divisions: Faculties > Sciences > School of Biosciences
Depositing User: O.O. Odanye
Date Deposited: 01 Jun 2009 19:56 UTC
Last Modified: 20 Jun 2019 10:30 UTC
Resource URI: https://kar.kent.ac.uk/id/eprint/19431 (The current URI for this page, for reference purposes)
  • Depositors only (login required):